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Laporte rule is a spectroscopic selection rule that only applies to centrosymmetric molecules (those with an inversion centre) and atoms. It states that
electronic transitions that conserve parity, either symmetry or antisymmetry with respect to an inversion centre — i.e., g (gerade = even (German)) → g, or u (ungerade = odd) → u respectively—are forbidden.
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complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many
metal-containing compounds, especially those
of transition metals, are coordination
complexes. A coordination
complex whose centre is a
metal atom ...
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Magnetic moments are often used in conjunction with
electronic spectra to gain information about the oxidation number and stereochemistry of the central
metal ion in coordination
complexes.
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Genius Deck Puzzle Challenges (Genius Decks) Unseen Influences How To Draw Dragons And Other Mythical Creatures Li+-doping in the Cu salt of deuterated DMe-DCNQI-d7 has shown drastic effects on electrical and magnetic properties. Undoped (DMe-DCNQI-d7)2Cu exhibits a first-order
metal-insulator (M-I)
transition …
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transition elements are important to the chemistry of living systems, the most familiar examples being iron, cobalt, copper, and molybdenum.Iron is by far the most widespread and important
transition metal that has a function in living systems; proteins containing iron participate in two main processes, oxygen transport and electron transfer ...
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BEYOND WORLDS END *Exists in both high and low spin states in thermal equilibrium. Bonding in Cp
Complexes. The normal bonding mode for Cp is 5 (pentahapto), for which several different resonance structures can be drawn for the bonding of an 5-Cp ligand to a
transition metal complex.The one on the right makes it easy to remember that a Cp ligand donates either 5 or 6 electrons to a
transition metal complex ...
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